Ethyl 1-oxo-1,2,3,4-tetrahydro-9H-carbazole-3-carboxylate
نویسندگان
چکیده
منابع مشابه
Ethyl 1-oxo-1,2,3,4-tetrahydro-9H-carbazole-3-carboxylate
The title compound, C(15)H(15)NO(3), contains a carbazole skeleton with an ethoxy-carbonyl group at the 3 position. In the indole ring system, the benzene and pyrrole rings are nearly coplanar, forming a dihedral angle of 1.95 (8)°. The cyclo-hexenone ring has an envelope conformation. In the crystal structure, pairs of strong N-H⋯O hydrogen bonds link the mol-ecules into centrosymmetric dimers...
متن کامل9-Ethyl-9H-carbazole-3-carbaldehyde
The title mol-ecule, C(15)H(13)NO, approximates a planar conformation except for the alkyl chain (ethyl group) bonded to the N atom with a maximum deviation from the least-squares plane through the 15 planar atoms of 0.120 (2) Å for the O atom. The distance of the formyl O atom from the plane of the carbazole ring is 0.227 (2) Å. The N-C bond lengths in the central ring are significantly differ...
متن کاملEthyl 4,9-dimethyl-9H-carbazole-3-carboxylate
In the title compound, C17H17NO2, the carbazole skeleton includes an eth-oxy-carbonyl group at the 3-position. The indole three-ring system is almost planar [maximum deviation = 0.065 (2) Å], and the ethyl ester group is inclined to its mean plane by 15.48 (2)°. In the crystal, there are π-π stacking inter-actions between parallel benzene rings and between parallel benzene and pyrrole rings of ...
متن کامل9-Ethyl-3-(2-methylbenzoyl)-9H-carbazole
In the title compound, C(22)H(19)NO, the dihedral angle between the benzene ring and the carbazole ring system 77.1 (1)°.. The crystal structure is stabilized by inter-molecular aromatic π-π inter-actions between the benzene ring and the pyrrole ring of the carbazole system of neighbouring mol-ecules [centroid-centroid distance = 3.617 (4) Å]. In addition, the crystal structure exhibits a weak ...
متن کاملEthyl 4-hydroxy-9-tosyl-9H-carbazole-3-carboxylate
In the title compound, C(22)H(19)NO(5)S, the carbazole skeleton is nearly planar [maximum deviation = 0.043 (1) Å] with the pyrrole ring oriented at dihedral angles of 2.32 (6) and 1.77 (6)° with respect to the adjacent benzene rings. The dihedral angle between the benzene ring of the tosyl group and the carbazole skeleton is 82.25 (5)°. Intra-molecular O-H⋯O hydrogen bonding results in the for...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2009
ISSN: 1600-5368
DOI: 10.1107/s160053680902385x